|
|
5-methoxygallic_acid + O2 <=> H+ + 2-Pyrone-4,6-dicarboxylate + methanol
|
1.13.11
1.13.11.8
protocatechuate 4,5-dioxygenase
|
–
–
|
| |
KEGG:
R04280
MetaCyc:
METHYLGALLATE-RXN
|
|
|
|
syringic_acid + tetrahydrofolate <=> 5-methoxygallic_acid + 5-methyltetrahydrofolate
|
2.1.1
2.1.1.341
vanillate/3-O-methylgallate O-demethylase
|
–
–
|
| |
BRENDA:
BS438468
KEGG:
R09270
MetaCyc:
RXN-10890
|
|
|
|
4-carboxy-2-hydroxyhexa-2,4-dienedioate <=> 4-carboxy-2-hydroxy-cis,cis-muconate
|
not assigned
|
–
|
| |
MetaCyc:
RXN-13747
|
|
|
|
4-oxalomesaconate <=> 4-carboxy-2-hydroxy-cis,cis-muconate
|
5.3.2.8
4-oxalomesaconate tautomerase
|
–
|
| |
BRENDA:
BR49625
KEGG:
R07839
MetaCyc:
RXN-9983
|
|
|
|
5-methoxygallic_acid + O2 <=> H+ + 4-carboxy-2-hydroxy-6-methoxy-6-oxohexa-2,4-dienoate
|
1.13.11
1.13.11.8
protocatechuate 4,5-dioxygenase
|
–
–
|
| |
KEGG:
R09272
MetaCyc:
RXN-10889
|
|
|
|
oxaloacetate + H+ <=> pyruvate + CO2
|
1.1.1.38
malate dehydrogenase (oxaloacetate-decarboxylating)
1.1.1.40
malate dehydrogenase (oxaloacetate-decarboxylating) (NADP+)
4.1.1.112
oxaloacetate decarboxylase
4.1.1.32
phosphoenolpyruvate carboxykinase (GTP)
4.1.2.52
4-hydroxy-2-oxoheptanedioate aldolase
4.1.3.16
4-hydroxy-2-oxoglutarate aldolase
4.1.3.17
4-hydroxy-4-methyl-2-oxoglutarate aldolase
4.1.3.39
4-hydroxy-2-oxovalerate aldolase
4.1.3.42
(4S)-4-hydroxy-2-oxoglutarate aldolase
4.1.3.43
4-hydroxy-2-oxohexanoate aldolase
4.4.1.1
cystathionine gamma-lyase
7.2.4.2
oxaloacetate decarboxylase (Na+ extruding)
|
–
–
–
–
–
–
–
–
–
–
–
–
|
| |
BRENDA:
BR289
KEGG:
R00217
MetaCyc:
OXALODECARB-RXN
SABIO-RK:
149
|
|
|
|
5-methoxygallic_acid + tetrahydrofolate <=> gallic_acid + 5-methyltetrahydrofolate
|
2.1.1.341
vanillate/3-O-methylgallate O-demethylase
|
–
|
| |
BRENDA:
BR52054
KEGG:
R09271
MetaCyc:
RXN-10892
|
|
|
|
4-carboxy-2-hydroxy-6-methoxy-6-oxohexa-2,4-dienoate + H2O <=> 4-carboxy-2-hydroxyhexa-2,4-dienedioate + methanol + H+
|
not assigned
|
–
|
| |
MetaCyc:
RXN-10893
|
|
|
|
2-Pyrone-4,6-dicarboxylate + H2O <=> 4-oxalomesaconate + H+
|
3.1.1.57
2-pyrone-4,6-dicarboxylate lactonase
|
–
|
| |
BRENDA:
BR47925
KEGG:
R04277
MetaCyc:
RXN-2462
|
|
