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sterigmatocystin biosynthesis

State Icon Reaction EC-Number Confidence maximal confidence score from EnzymeDetector
(4S,8R)-2,19-dihydroxy-7,9-dioxapentacyclo[10.8.0.03,10.04,8.04,19]icosa-1,3(10),5,11,14,16-hexaene-13,18,20-trione + O2 + NADPH + H+ <=> (4S,8R)-2,20-dihydroxy-7,9,13-trioxapentacyclo[10.9.0.03,10.04,8.015,20]henicosa-1,3(10),5,11,15,17-hexaene-14,19,21-trione + H2O + NADP+ not assigned

S-adenosyl-L-methionine + 6-demethylsterigmatocystin <=> H+ + S-adenosyl-L-homocysteine + sterigmatocystin 2.1.1.109 demethylsterigmatocystin 6-O-methyltransferase

16-deoxyversicolorin_A_epoxide <=> (4S,8R)-2,19-dihydroxy-7,9-dioxapentacyclo[10.8.0.03,10.04,8.04,19]icosa-1,3(10),5,11,14,16-hexaene-13,18,20-trione not assigned

(4S,8R)-2,20-dihydroxy-7,9,13-trioxapentacyclo[10.9.0.03,10.04,8.015,20]henicosa-1,3(10),5,11,15,17-hexaene-14,19,21-trione <=> 6-demethylsterigmatocystin + CO2 4.1.1

16-deoxyversicolorin_A + reduced_[NADPH-hemoprotein_reductase] + O2 <=> 16-deoxyversicolorin_A_epoxide + oxidized_[NADPH-hemoprotein_reductase] + H2O 1.14.14

(4S,8R,16R)-2,13,16,20-tetrahydroxy-7,9-dioxapentacyclo[10.8.0.03,10.04,8.014,19]icosa-1(12),2,5,10,13,19-hexaen-18-one + acceptor <=> 16-deoxyversicolorin_A + H2O + reduced_acceptor not assigned

(4S,8R)-2,13,16,20-tetrahydroxy-7,9-dioxapentacyclo[10.8.0.03,10.04,8.04,19]icosa-1(12),2,5,10,13,16,19-heptaen-18-one + NADPH + H+ <=> (4S,8R,16R)-2,13,16,20-tetrahydroxy-7,9-dioxapentacyclo[10.8.0.03,10.04,8.014,19]icosa-1(12),2,5,10,13,19-hexaen-18-one + NADP+ 1.3.1

Versicolorin_A + reduced_acceptor + H+ <=> (4S,8R)-2,13,16,20-tetrahydroxy-7,9-dioxapentacyclo[10.8.0.03,10.04,8.04,19]icosa-1(12),2,5,10,13,16,19-heptaen-18-one + acceptor not assigned

versicolorin_B + NADP+ <=> Versicolorin_A + NADPH + H+ 1.3.1

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