|
|
(2E,6E)-farnesyl_diphosphate <=> pentalenene + diphosphate
|
4.2.3.7
pentalenene synthase
|
–
|
| |
BRENDA:
BR48354
KEGG:
R02305
MetaCyc:
PENTALENENE-SYNTHASE-RXN
|
|
|
|
pentalenolactone_D + O2 + 2-oxoglutarate <=> pentalenolactone_E + succinate + CO2 + H2O
|
1.14.11.36
pentalenolactone F synthase
|
–
|
| |
BRENDA:
BR50259
KEGG:
R10143
MetaCyc:
RXN-12660
|
|
|
|
pentalenolactone_F + O2 + reduced_ferredoxin_[iron-sulfur]_cluster + H+ <=> pentalenolactone + H2O + oxidized_ferredoxin
|
1.14.19.8
pentalenolactone synthase
|
–
|
| |
BRENDA:
BR50241
KEGG:
R10162
MetaCyc:
RXN-12653
|
|
|
|
pentalen-13-al + reduced_ferredoxin_[iron-sulfur]_cluster + O2 + H+ <=> (+/-)-1-deoxypentalenic_acid + oxidized_ferredoxin + H2O
|
1.14.15
|
–
|
| |
MetaCyc:
RXN-12652
|
|
|
|
1-deoxy-11beta-hydroxypentalenic_acid + NAD+ <=> 1-deoxy-11-oxopentalenate + NADH + H+
|
1.1.1.340
1-deoxy-11beta-hydroxypentalenate dehydrogenase
|
–
|
| |
BRENDA:
BR50233
KEGG:
R10156
MetaCyc:
RXN-12658
|
|
|
|
pentalenene + reduced_ferredoxin_[iron-sulfur]_cluster + O2 + H+ <=> pentalen-13-ol + oxidized_ferredoxin + H2O
|
1.14.15.32
pentalenene oxygenase
|
–
|
| |
BRENDA:
BR49820
KEGG:
R09812
MetaCyc:
RXN-12649
|
|
|
|
pentalenolactone_E + O2 + 2-oxoglutarate <=> pentalenolactone_F + succinate + CO2
|
1.14.11
1.14.11.36
pentalenolactone F synthase
|
–
–
|
| |
BRENDA:
BR50260
KEGG:
R10144
MetaCyc:
RXN-12655
|
|
|
|
pentalen-13-ol + reduced_ferredoxin_[iron-sulfur]_cluster + H+ + O2 <=> pentalen-13-al + oxidized_ferredoxin + H2O
|
1.14.15.32
pentalenene oxygenase
|
–
|
| |
BRENDA:
BR49821
KEGG:
R09813
MetaCyc:
RXN-12650
|
|
|
|
(+/-)-1-deoxypentalenic_acid + 2-oxoglutarate + O2 <=> 1-deoxy-11beta-hydroxypentalenic_acid + succinate + CO2
|
1.14.11.35
1-deoxypentalenic acid 11beta-hydroxylase
|
–
|
| |
BRENDA:
BR50257
KEGG:
R10157
MetaCyc:
RXN-12651
|
|
|
|
1-deoxy-11-oxopentalenate + O2 + NADPH + H+ <=> pentalenolactone_D + H2O + NADP+
|
1.14.13.170
pentalenolactone D synthase
|
–
|
| |
BRENDA:
BR50265
KEGG:
R10154
MetaCyc:
RXN-12654
|
|
