|
|
malonyl-CoA + (S)-methylmalonyl-CoA + NADPH + H+ <=> narbonolide + CoA + CO2 + H2O + NADP+
|
2.3.1.240
narbonolide synthase
|
–
|
| |
BRENDA:
BR51190
KEGG:
R06459
MetaCyc:
RXN-15105
|
|
|
|
TDP-3-dimethylamino-4,6-dideoxy-alpha-D-glucopyranose + narbonolide <=> narbomycin + dTDP + H+
|
2.4.1.277
10-deoxymethynolide desosaminyltransferase
|
–
|
| |
BRENDA:
BS415775
KEGG:
R06461
MetaCyc:
RXN-15102
|
|
|
|
pikromycin + O2 + reduced_ferredoxin_[iron-sulfur]_cluster + H+ <=> novapikromyin + oxidized_ferredoxin + H2O
|
1.14.15.33
pikromycin synthase
|
–
|
| |
MetaCyc:
RXN-15106
|
|
|
|
narbomycin + O2 + reduced_ferredoxin_[iron-sulfur]_cluster + H+ <=> pikromycin + oxidized_ferredoxin + H2O
|
1.14.15.33
pikromycin synthase
|
–
|
| |
BRENDA:
BR50917
KEGG:
R06464
MetaCyc:
RXN-15099
|
|
|
|
narbomycin + O2 + reduced_ferredoxin_[iron-sulfur]_cluster + H+ <=> neopikromycin + oxidized_ferredoxin + H2O
|
1.14.15.33
pikromycin synthase
|
–
|
| |
BRENDA:
BR50918
KEGG:
R10626
MetaCyc:
RXN-15107
|
|
|
|
neopikromycin + O2 + reduced_ferredoxin_[iron-sulfur]_cluster + H+ <=> novapikromyin + oxidized_ferredoxin + H2O
|
1.14.15.33
pikromycin synthase
|
–
|
| |
MetaCyc:
RXN-15110
|
|
