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leucine-derived hydroxynitrile glucoside biosynthesis

State Icon Reaction EC-Number Confidence maximal confidence score from EnzymeDetector
isovaleronitrile + reduced_[NADPH-hemoprotein_reductase] + O2 <=> 3-hydroxy-3-methylbutanenitrile + oxidized_[NADPH-hemoprotein_reductase] + H2O not assigned

L-leucine + O2 + reduced_[NADPH-hemoprotein_reductase] <=> N-hydroxy-L-leucine + oxidized_[NADPH-hemoprotein_reductase] + H+ + H2O not assigned

UDP-glucose + (Z)-4-hydroxy-3-methylbut-2-enenitrile <=> osmaronin + UDP + H+ 2.4.1.M51

(Z)-4-hydroxy-3-methylbut-2-enenitrile + reduced_[NADPH-hemoprotein_reductase] + O2 <=> 4-hydroxy-3-(hydroxymethyl)-2-butenenitrile + oxidized_[NADPH-hemoprotein_reductase] + H2O not assigned

UDP-glucose + (2R)-2-hydroxy-3-methylbutanenitrile <=> epiheterodendrin + UDP + H+ 2.4.1.M50

N,N-dihydroxy-L-leucine + H+ <=> (E/Z)-isovaleraldoxime + CO2 + H2O not assigned

3-hydroxy-3-methylbutanenitrile <=> 3-methyl-2-butenenitrile + H2O not assigned

(Z)-3-methylbutanaloxime <=> isovaleronitrile + H2O not assigned

UDP-glucose + (S)-4-hydroxy-3-methylbutanenitrile <=> dihydroosmaronin + UDP + H+ 2.4.1.M52

(E/Z)-isovaleraldoxime <=> (Z)-3-methylbutanaloxime not assigned

3-methyl-2-butenenitrile + reduced_[NADPH-hemoprotein_reductase] + O2 <=> (Z)-4-hydroxy-3-methylbut-2-enenitrile + oxidized_[NADPH-hemoprotein_reductase] + H2O not assigned

UDP-glucose + 4-hydroxy-3-(hydroxymethyl)-2-butenenitrile <=> sutherlandin + UDP + H+ 2.4.1

isovaleronitrile + reduced_[NADPH-hemoprotein_reductase] + O2 <=> (2R)-2-hydroxy-3-methylbutanenitrile + oxidized_[NADPH-hemoprotein_reductase] + H2O not assigned

isovaleronitrile + reduced_[NADPH-hemoprotein_reductase] + O2 <=> (S)-4-hydroxy-3-methylbutanenitrile + oxidized_[NADPH-hemoprotein_reductase] + H2O not assigned

N-hydroxy-L-leucine + O2 + reduced_[NADPH-hemoprotein_reductase] <=> N,N-dihydroxy-L-leucine + oxidized_[NADPH-hemoprotein_reductase] + H2O not assigned

UDP-glucose + 3-hydroxy-3-methylbutanenitrile <=> epidermin + UDP + H+ 2.4.1.M53

Visualization of the pathway