|
|
beta-methylenecyclopropyl_pyruvate + L-alanine <=> hypoglycin + pyruvate
|
2.6.1
|
–
|
| |
MetaCyc:
RXN-9175
|
|
|
|
3-hydroxy-3-carboxy-4,5-cyclopropylhex-5-enoate <=> 2-hydroxy-3-carboxy-4,5-cyclopropylhex-5-enoate
|
5.4.4
|
–
|
| |
MetaCyc:
RXN-9172
|
|
|
|
2-oxopent-4-enoate + acceptor <=> 2-oxopenta-3,4-dienoate + reduced_acceptor
|
1
|
–
|
| |
MetaCyc:
RXN-9169
|
|
|
|
2-oxobutyrate <=> 5-hydroxy-2-oxopentanoate
|
not assigned
|
–
|
| |
MetaCyc:
RXN-9167
|
|
|
|
2-hydroxy-3-carboxy-4,5-cyclopropylhex-5-enoate + acceptor <=> 2-oxo-3-carboxy-4,5-cyclopropylhex-5-enoate + reduced_acceptor
|
1.1
|
–
|
| |
MetaCyc:
RXN-9173
|
|
|
|
glutathione + hypoglycin <=> hypoglycin_B + Cys-Gly
|
2.3.2.2
gamma-glutamyltransferase
|
–
|
| |
BRENDA:
BS423687
MetaCyc:
RXN-9157
|
|
|
|
2-oxohexa-4,5-cyclopropyl-5-enoate + aminated_amino_group_donor <=> L-alpha-(methylenecyclopropyl)-glycine + deaminated_amino_group_donor
|
2.6.1
|
–
|
| |
MetaCyc:
RXN-9189
|
|
|
|
2-oxopenta-3,4-dienoate <=> 2-oxohexa-4,5-cyclopropyl-5-enoate
|
not assigned
|
–
|
| |
MetaCyc:
RXN-9170
|
|
|
|
H+ + 2-oxo-3-carboxy-4,5-cyclopropylhex-5-enoate <=> beta-methylenecyclopropyl_pyruvate + CO2
|
4.1.1
|
–
|
| |
MetaCyc:
RXN-9174
|
|
|
|
2-oxohexa-4,5-cyclopropyl-5-enoate + acetyl-CoA + H2O <=> H+ + 3-hydroxy-3-carboxy-4,5-cyclopropylhex-5-enoate + CoA
|
2.3
|
–
|
| |
MetaCyc:
RXN-9171
|
|
|
|
2-iminobutanoate + H2O + H+ <=> 2-oxobutyrate + NH3
|
3.5.99.10
2-iminobutanoate/2-iminopropanoate deaminase
3.5.99.7
1-aminocyclopropane-1-carboxylate deaminase
4.3.1.19
threonine ammonia-lyase
4.4.1.1
cystathionine gamma-lyase
4.4.1.2
homocysteine desulfhydrase
|
–
–
–
–
–
|
| |
BRENDA:
BR49538
KEGG:
R11098
MetaCyc:
RXN-15123
|
|
|
|
2-aminobut-2-enoate <=> 2-iminobutanoate
|
3.5.99.7
1-aminocyclopropane-1-carboxylate deaminase
4.3.1.19
threonine ammonia-lyase
4.4.1.1
cystathionine gamma-lyase
4.4.1.2
homocysteine desulfhydrase
|
–
–
–
–
|
| |
BRENDA:
BR50837
KEGG:
R11101
MetaCyc:
RXN-15121
|
|
|
|
L-threonine <=> 2-aminobut-2-enoate + H2O + H+
|
4.3.1.19
threonine ammonia-lyase
|
–
|
| |
BRENDA:
BR50836
MetaCyc:
RXN-15122
|
|
|
|
5-hydroxy-2-oxopentanoate <=> 2-oxopent-4-enoate + H2O
|
not assigned
|
–
|
| |
MetaCyc:
RXN-9168
|
|
