|
|
(2E)-2-[(2E)-2-azanidyl-3-sulfanylprop-2-enamido]-3-[HlmE_non-ribosomal_peptide_synthetase] <=> 4-amino-2-(methanethioyl)-5-oxo-3-sulfanylpyrrolidine-2-carboxyl-[HlmE_non-ribosomal_peptide_synthetase]
|
not assigned
|
–
|
| |
MetaCyc:
RXN-16877
|
|
|
|
(5E)-3-imino-4-sulfanyl-5-(sulfanylmethylidene)pyrrolidin-2-one <=> dithioholothin
|
not assigned
|
–
|
| |
MetaCyc:
RXN-16871
|
|
|
|
(2E)-2-amino-3-sulfanylprop-2-enoyl-[HlmE_non-ribosomal_peptide_synthetase] + L-cysteine + acceptor + ATP <=> (2E)-2-[(2E)-2-azanidyl-3-sulfanylprop-2-enamido]-3-[HlmE_non-ribosomal_peptide_synthetase] + reduced_acceptor + AMP + diphosphate + H+
|
6.3.2
|
–
|
| |
MetaCyc:
RXN-16876
|
|
|
|
dithioholothin + O2 <=> holothin + H2O2
|
1.8.3.M1
|
–
|
| |
MetaCyc:
RXN-16869
|
|
|
|
4-amino-2-(methanethioyl)-5-oxo-3-sulfanylpyrrolidine-2-carboxyl-[HlmE_non-ribosomal_peptide_synthetase] + H2O <=> 4-amino-2-(methanethioyl)-5-oxo-3-sulfanylpyrrolidine-2-carboxylate + HlmE_non-ribosomal_peptide_synthetase + H+
|
3.1.2
|
–
|
| |
MetaCyc:
RXN-16878
|
|
|
|
L-cysteinyl-[HlmE_non-ribosomal_peptide_synthetase] + acceptor <=> (2E)-2-amino-3-sulfanylprop-2-enoyl-[HlmE_non-ribosomal_peptide_synthetase] + reduced_acceptor
|
not assigned
|
–
|
| |
MetaCyc:
RXN-16875
|
|
|
|
acetyl-CoA + dithioholothin <=> dithioholomycin + CoA
|
2.3.1
|
–
|
| |
MetaCyc:
RXN-16879
|
|
|
|
acetyl-CoA + holothin <=> holomycin + CoA
|
2.3.1
|
–
|
| |
MetaCyc:
RXN-16663
|
|
|
|
4-amino-2-(methanethioyl)-5-oxo-3-sulfanylpyrrolidine-2-carboxylate + H+ <=> (5E)-3-amino-4-sulfanyl-5-(sulfanylmethylidene)pyrrolidin-2-one + CO2
|
4.1.1
|
–
|
| |
MetaCyc:
RXN-16873
|
|
|
|
HlmE_non-ribosomal_peptide_synthetase + L-cysteine + ATP <=> L-cysteinyl-[HlmE_non-ribosomal_peptide_synthetase] + AMP + diphosphate
|
6.3.2
|
–
|
| |
MetaCyc:
RXN-16874
|
|
|
|
dithioholomycin + O2 <=> holomycin + H2O2
|
1.8.3.M1
|
–
|
| |
MetaCyc:
RXN-16870
|
|
|
|
(5E)-3-amino-4-sulfanyl-5-(sulfanylmethylidene)pyrrolidin-2-one + acceptor <=> (5E)-3-imino-4-sulfanyl-5-(sulfanylmethylidene)pyrrolidin-2-one + H+ + reduced_acceptor
|
1.4.99
|
–
|
| |
MetaCyc:
RXN-16872
|
|
