|
|
(E)-1-(L-Cysteinylglycine-S-yl)-N-hydroxy-omega-(methylsulfanyl)alkane-1-imine + H2O <=> an_(E)-omega-(methylthio)alkyl-thiohydroximate + L-seryl-glycine
|
4.4.1.M2
|
–
|
| |
MetaCyc:
RXN-11438
|
|
|
|
3-hydroxypropyl-glucosinolate + sinapoyl-CoA <=> 3-sinapoyloxypropylglucosinolate + CoA
|
not assigned
|
–
|
| |
MetaCyc:
RXN-11445
|
|
|
|
glucoiberin + O2 <=> H+ + sinigrin + methanesulfonate
|
1.14.11.M8
|
–
|
| |
MetaCyc:
RXN-2222
|
|
|
|
L-homomethionine + O2 + reduced_[NADPH-hemoprotein_reductase] <=> (E)-4-(methylsulfanyl)butanal_oxime + CO2 + H2O + oxidized_[NADPH-hemoprotein_reductase]
|
1.14.14.42
homomethionine N-monooxygenase
|
–
|
| |
MetaCyc:
RXN-2206
|
|
|
|
UDP-glucose + an_(E)-omega-(methylthio)alkyl-thiohydroximate <=> H+ + an_aliphatic_desulfoglucosinolate + UDP
|
2.4.1.195
N-hydroxythioamide S-beta-glucosyltransferase
|
–
|
| |
BRENDA:
BR52365
KEGG:
R08668;
R12045
MetaCyc:
RXN-2208
|
|
|
|
glucoiberin + O2 + H2O <=> 3-hydroxypropyl-glucosinolate + methanesulfonate + H+
|
1.14.11.M9
|
–
|
| |
MetaCyc:
RXN-2223
|
|
|
|
(E)-1-(L-Cysteinylglycine-S-yl)-N-hydroxy-omega-(methylsulfanyl)alkane-1-imine + H2O <=> S-(4-Methylthiobutylthiohydroximoyl)-L-cysteine + glycine
|
3.4.13.23
cysteinylglycine-S-conjugate dipeptidase
|
–
|
| |
MetaCyc:
RXN-19589
|
|
|
|
a_1-aci-nitro-omega-(methylthio)alkane + glutathione <=> (E)-1-(glutathione-S-yl)-omega-(methylthio)alkylhydroximate + H2O
|
1.14.14.43
(methylsulfanyl)alkanaldoxime N-monooxygenase
|
–
|
| |
BRENDA:
BR51953
KEGG:
R11652
MetaCyc:
RXN-11422
|
|
|
|
3''-phosphoadenylyl-sulfate + an_aliphatic_desulfoglucosinolate <=> adenosine_3,5''-bisphosphate + H+ + glucoiberverin
|
2.8.2
2.8.2.38
aliphatic desulfoglucosinolate sulfotransferase
|
–
–
|
| |
KEGG:
R08669
MetaCyc:
RXN-2209
|
|
|
|
S-(4-Methylthiobutylthiohydroximoyl)-L-cysteine + H2O <=> an_(E)-omega-(methylthio)alkyl-thiohydroximate + pyruvate + NH3
|
4.4.1
4.4.1.13
cysteine-S-conjugate beta-lyase
|
–
–
|
| |
KEGG:
R08667
MetaCyc:
RXN-8052
|
|
|
|
glucoiberverin + O2 + NADPH + H+ <=> glucoiberin + NADP+ + H2O
|
1.14.13.237
aliphatic glucosinolate S-oxygenase
|
–
|
| |
MetaCyc:
RXN-2221
|
|
|
|
(E)-4-(methylsulfanyl)butanal_oxime + O2 + reduced_[NADPH-hemoprotein_reductase] <=> a_1-aci-nitro-omega-(methylthio)alkane + H2O + oxidized_[NADPH-hemoprotein_reductase]
|
not assigned
|
–
|
| |
MetaCyc:
RXN-11414
|
|
|
|
3-hydroxypropyl-glucosinolate + benzoyl-CoA <=> glucomalcommin + CoA
|
not assigned
|
–
|
| |
MetaCyc:
RXN-2224
|
|
|
|
(E)-1-(glutathione-S-yl)-omega-(methylthio)alkylhydroximate + H2O <=> (E)-1-(L-Cysteinylglycine-S-yl)-N-hydroxy-omega-(methylsulfanyl)alkane-1-imine + L-glutamate
|
3.4.19.16
glucosinolate gamma-glutamyl hydrolase
|
–
|
| |
KEGG:
R11792
MetaCyc:
RXN-11430
|
|
