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glucosinolate biosynthesis from homomethionine

State Icon Reaction EC-Number Confidence maximal confidence score from EnzymeDetector
(E)-1-(L-Cysteinylglycine-S-yl)-N-hydroxy-omega-(methylsulfanyl)alkane-1-imine + H2O <=> an_(E)-omega-(methylthio)alkyl-thiohydroximate + L-seryl-glycine 4.4.1.M2

3-hydroxypropyl-glucosinolate + sinapoyl-CoA <=> 3-sinapoyloxypropylglucosinolate + CoA not assigned

glucoiberin + O2 <=> H+ + sinigrin + methanesulfonate 1.14.11.M8

L-homomethionine + O2 + reduced_[NADPH-hemoprotein_reductase] <=> (E)-4-(methylsulfanyl)butanal_oxime + CO2 + H2O + oxidized_[NADPH-hemoprotein_reductase] 1.14.14.42 homomethionine N-monooxygenase

UDP-glucose + an_(E)-omega-(methylthio)alkyl-thiohydroximate <=> H+ + an_aliphatic_desulfoglucosinolate + UDP 2.4.1.195 N-hydroxythioamide S-beta-glucosyltransferase

glucoiberin + O2 + H2O <=> 3-hydroxypropyl-glucosinolate + methanesulfonate + H+ 1.14.11.M9

(E)-1-(L-Cysteinylglycine-S-yl)-N-hydroxy-omega-(methylsulfanyl)alkane-1-imine + H2O <=> S-(4-Methylthiobutylthiohydroximoyl)-L-cysteine + glycine 3.4.13.23 cysteinylglycine-S-conjugate dipeptidase

a_1-aci-nitro-omega-(methylthio)alkane + glutathione <=> (E)-1-(glutathione-S-yl)-omega-(methylthio)alkylhydroximate + H2O 1.14.14.43 (methylsulfanyl)alkanaldoxime N-monooxygenase

3''-phosphoadenylyl-sulfate + an_aliphatic_desulfoglucosinolate <=> adenosine_3,5''-bisphosphate + H+ + glucoiberverin 2.8.2
2.8.2.38 aliphatic desulfoglucosinolate sulfotransferase


S-(4-Methylthiobutylthiohydroximoyl)-L-cysteine + H2O <=> an_(E)-omega-(methylthio)alkyl-thiohydroximate + pyruvate + NH3 4.4.1
4.4.1.13 cysteine-S-conjugate beta-lyase


glucoiberverin + O2 + NADPH + H+ <=> glucoiberin + NADP+ + H2O 1.14.13.237 aliphatic glucosinolate S-oxygenase

(E)-4-(methylsulfanyl)butanal_oxime + O2 + reduced_[NADPH-hemoprotein_reductase] <=> a_1-aci-nitro-omega-(methylthio)alkane + H2O + oxidized_[NADPH-hemoprotein_reductase] not assigned

3-hydroxypropyl-glucosinolate + benzoyl-CoA <=> glucomalcommin + CoA not assigned

(E)-1-(glutathione-S-yl)-omega-(methylthio)alkylhydroximate + H2O <=> (E)-1-(L-Cysteinylglycine-S-yl)-N-hydroxy-omega-(methylsulfanyl)alkane-1-imine + L-glutamate 3.4.19.16 glucosinolate gamma-glutamyl hydrolase

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