|
|
S-adenosyl-L-methionine + 6-hydroxytryprostatin_B <=> S-adenosyl-L-homocysteine + tryprostatin_A + H+
|
2.1.1.293
6-hydroxytryprostatin B O-methyltransferase
|
–
|
| |
BRENDA:
BR50795
KEGG:
R10588
MetaCyc:
RXN-14927
|
|
|
|
tryprostatin_A + reduced_flavodoxin + O2 <=> fumitremorgin_C + flavin + 2 H2O
|
1.14.19.71
fumitremorgin C synthase
|
–
|
| |
BRENDA:
BR50590
KEGG:
R10416
|
|
|
|
tryprostatin_B + reduced_flavodoxin + O2 <=> 6-hydroxytryprostatin_B + flavin + H2O
|
1.14.14.118
tryprostatin B 6-hydroxylase
|
–
|
| |
BRENDA:
BR50525
KEGG:
R10321
|
|
|
|
fumitremorgin_C + 2 reduced_flavodoxin + 2 O2 <=> 12alpha,13alpha-dihydroxyfumitremorgin_C + 2 flavin + 2 H2O
|
1.14.14.119
fumitremorgin C monooxygenase
|
–
|
| |
BRENDA:
BR50576
KEGG:
R10414
|
|
|
|
dimethylallyl_diphosphate + verruculogen <=> fumitremorgin_A + diphosphate
|
2.5.1.107
verruculogen prenyltransferase
|
–
|
| |
BRENDA:
BR50541
KEGG:
R10341
MetaCyc:
RXN-14421
|
|
|
|
fumitremorgin_B + 2-oxoglutarate + 2 O2 + reduced_acceptor <=> verruculogen + succinate + CO2 + H2O + acceptor
|
1.14.11.38
verruculogen synthase
|
–
|
| |
BRENDA:
BR50568;
BS421968
KEGG:
R10445
|
|
|
|
dimethylallyl_diphosphate + brevianamide_F <=> diphosphate + tryprostatin_B
|
2.5.1.106
tryprostatin B synthase
|
–
|
| |
BRENDA:
BR50540
KEGG:
R10340
MetaCyc:
RXN-14418
|
|
|
|
dimethylallyl_diphosphate + 12alpha,13alpha-dihydroxyfumitremorgin_C <=> diphosphate + fumitremorgin_B
|
2.5.1.110
12alpha,13alpha-dihydroxyfumitremorgin C prenyltransferase
|
–
|
| |
BRENDA:
BR50670
KEGG:
R10457
MetaCyc:
RXN-14420
|
|
