|
|
acyl-CoA + H2O <=> an_(R)-2-alkyl-3-oxoalkanoate + CoA + H+
|
2.3.3.20
acyl-CoA:acyl-CoA alkyltransferase
|
–
|
| |
BRENDA:
BR52320
KEGG:
R11958
MetaCyc:
RXN-18555
|
|
|
|
a_(2R,3S)-2-alkyl-3-hydroxyalkanoate + NADP+ <=> an_(R)-2-alkyl-3-oxoalkanoate + NADPH + H+
|
1.1.1.412
2-alkyl-3-oxoalkanoate reductase
|
–
|
| |
BRENDA:
BR52124;
BS440030
KEGG:
R11774
MetaCyc:
RXN-18556
|
|
|
|
a_cis-3-alkyl-4-alkyloxetan-2-one <=> a_cis-alkene + CO2
|
4.1.1.114
cis-3-alkyl-4-alkyloxetan-2-one decarboxylase
|
–
|
| |
BRENDA:
BR52592
MetaCyc:
RXN-18558
|
|
|
|
a_(2R,3S)-2-alkyl-3-hydroxyalkanoate + ATP <=> a_cis-3-alkyl-4-alkyloxetan-2-one + AMP + diphosphate
|
6.1.3.1
olefin beta-lactone synthetase
|
–
|
| |
BRENDA:
BR52231
KEGG:
R11775
MetaCyc:
RXN-18557
|
|
