|
|
O2 + (S)-reticuline <=> H+ + H2O2 + (S)-scoulerine
|
1.21.3.3
reticuline oxidase
|
–
|
|
BRENDA:
BR36965
KEGG:
R03831
MetaCyc:
RETICULINE-OXIDASE-RXN
|
|
|
|
(S)-N-methylcanadine + O2 + reduced_[NADPH-hemoprotein_reductase] <=> Allocryptopine + H2O + oxidized_[NADPH-hemoprotein_reductase] + H+
|
1.14.14.97
methyltetrahydroprotoberberine 14-monooxygenase
|
–
|
|
MetaCyc:
1.14.13.37-RXN
|
|
|
|
6-hydroxyallocryptopine <=> Dihydrochelerythrine + H2O
|
not assigned
|
–
|
|
MetaCyc:
RXN-15541
|
|
|
|
chelerythrine + NADPH <=> Dihydrochelerythrine + NADP+
|
1.3.1.107
sanguinarine reductase
|
–
|
|
BRENDA:
BS430028
MetaCyc:
RXN-15543
|
|
|
|
S-adenosyl-L-methionine + (S)-scoulerine <=> H+ + S-adenosyl-L-homocysteine + (S)-tetrahydrocolumbamine
|
2.1.1.117
(S)-scoulerine 9-O-methyltransferase
|
–
|
|
BRENDA:
BR1438
KEGG:
R03835
MetaCyc:
2.1.1.117-RXN
SABIO-RK:
3591
|
|
|
|
S-adenosyl-L-methionine + (S)-canadine <=> (S)-N-methylcanadine + S-adenosyl-L-homocysteine
|
2.1.1.122
(S)-tetrahydroprotoberberine N-methyltransferase
|
–
|
|
KEGG:
R08789
MetaCyc:
RXN-13806
|
|
|
|
(S)-tetrahydrocolumbamine + O2 + reduced_[NADPH-hemoprotein_reductase] <=> (S)-canadine + H2O + oxidized_[NADPH-hemoprotein_reductase]
|
1.14.19.68
(S)-canadine synthase
|
–
|
|
MetaCyc:
1.1.3.36-RXN
|
|
|
|
Dihydrochelerythrine + O2 + H+ <=> chelerythrine + H2O2
|
1.5.3.12
dihydrobenzophenanthridine oxidase
|
–
|
|
BRENDA:
BS424776
MetaCyc:
RXN-15542
|
|
|
|
Allocryptopine + reduced_[NADPH-hemoprotein_reductase] + O2 <=> 6-hydroxyallocryptopine + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
1.14.14
|
–
|
|
MetaCyc:
RXN-13828
|
|