|
|
(S)-DNPA + reduced_acceptor <=> 5-deoxy-dihydrokalafungin + acceptor
|
not assigned
|
–
|
| |
MetaCyc:
RXN1A0-6316
|
|
|
|
malonyl-CoA + polyketide-[acp] + H+ <=> 3,5,7,9,11,13,15-hepta-oxo-hexadecanoyl-[PKS-acp] + CO2 + CoA
|
2.3.1
|
–
|
| |
MetaCyc:
RXN1A0-6297
|
|
|
|
4-(3''-acetyl-5''-hydroxy-4''-oxo-1,4''-dihydronapthalen-2''-yl)-3-oxobutanoate-[PKS-acp] + H2O <=> 4-(3''-acetyl-5''-hydroxy-4''-oxo-1,4''-dihydronapthalen-2''-yl)-3-oxobutanoate + polyketide-[acp] + H+
|
3.1.2
|
–
|
| |
MetaCyc:
RXN1A0-6307
|
|
|
|
4-(3''-acetyl-5''-hydroxy-4''-oxo-1,4''-dihydronapthalen-2''-yl)-3-oxobutanoate + NADPH + H+ <=> (S)-4-(3''-acetyl-5''-hydroxy-4''-oxo-1,4''-dihydronapthalen-2''-yl)-3-hydroxybutanoate + NADP+
|
1.1.1
|
–
|
| |
MetaCyc:
RXN1A0-6310
|
|
|
|
Dihydrokalafungin_dihydroquinone_form + O2 + FMNH2 <=> 1,3,6,8-Tetrahydroxynaphthalene + H2O + FMN + H+
|
1.14.14
|
–
|
| |
KEGG:
R09313
MetaCyc:
RXN-18115
|
|
|
|
(3''-hydroxy-2''-(3''''-oxobutanoyl)phenyl)-3,5-dioxohexanethioate-[PKS-acp] <=> 4-(3''-acetyl-5''-hydroxy-4''-oxo-1,4''-dihydronapthalen-2''-yl)-3-oxobutanoate-[PKS-acp] + H2O
|
4.2.1
|
–
|
| |
MetaCyc:
RXN-15199
|
|
|
|
9-hydroxy-3,5,7,11,13,15-hexaoxohexadecanoyl-[PKS-acp] + NADP+ <=> 3,5,7,9,11,13,15-hepta-oxo-hexadecanoyl-[PKS-acp] + NADPH + H+
|
1.3.1
|
–
|
| |
MetaCyc:
RXN1A0-6303
|
|
|
|
(S)-4-(3''-acetyl-5''-hydroxy-4''-oxo-1,4''-dihydronapthalen-2''-yl)-3-hydroxybutanoate <=> 2-((1R,3S),-1,9''-dihydroxy-1''-methyl-10''-oxo-3,4,5,10''-tetrahydro-1H-benzo[g]isochromen-3''-yl)acetate
|
5.5.1
|
–
|
| |
KEGG:
R09307
MetaCyc:
RXN1A0-6312
|
|
|
|
5-deoxy-dihydrokalafungin + O2 + FMNH2 <=> Dihydrokalafungin_dihydroquinone_form + H2O + FMN + H+
|
1.14.14
|
–
|
| |
MetaCyc:
RXN-18114
|
|
|
|
1,3,6,8-Tetrahydroxynaphthalene + acceptor <=> Actinorhodin + reduced_acceptor
|
not assigned
|
–
|
| |
MetaCyc:
RXN-18116
|
|
|
|
2-((1R,3S),-1,9''-dihydroxy-1''-methyl-10''-oxo-3,4,5,10''-tetrahydro-1H-benzo[g]isochromen-3''-yl)acetate <=> (S)-DNPA + H2O
|
4.2.1
|
–
|
| |
KEGG:
R09308
MetaCyc:
RXN1A0-6314
|
|
|
|
9-hydroxy-3,5,7,11,13,15-hexaoxohexadecanoyl-[PKS-acp] <=> (3''-hydroxy-2''-(3''''-oxobutanoyl)phenyl)-3,5-dioxohexanethioate-[PKS-acp] + H2O
|
4.2.1
|
–
|
| |
MetaCyc:
RXN1A0-6305
|
|
