|
|
Gamma-hydroxyvalerate + CoA + ATP <=> 4-hydroxypentanoyl-CoA + AMP + diphosphate
|
6.2.1.2
medium-chain acyl-CoA ligase
|
–
|
| |
MetaCyc:
RXN-19192
|
|
|
|
levulinic_acid + CoA + ATP <=> 4-oxopentanoyl-CoA + AMP + diphosphate
|
6.2.1.2
medium-chain acyl-CoA ligase
|
–
|
| |
MetaCyc:
RXN-19185
|
|
|
|
4-hydroxypentanoyl-CoA + NADP+ <=> 4-oxopentanoyl-CoA + NADPH + H+
|
1.1.1.M44
|
–
|
| |
MetaCyc:
RXN-19186
|
|
|
|
beta-methylvinylacetyl-CoA <=> 2-pentenoyl-CoA
|
not assigned
|
–
|
| |
MetaCyc:
RXN-19189
|
|
|
|
(3S)-3-hydroxyacyl-CoA <=> trans-2-enoyl-CoA + H2O
|
4.2.1.119
enoyl-CoA hydratase 2
4.2.1.134
very-long-chain (3R)-3-hydroxyacyl-CoA dehydratase
4.2.1.17
enoyl-CoA hydratase
4.2.1.74
long-chain-enoyl-CoA hydratase
|
–
–
–
–
|
| |
BRENDA:
BR3387;
BR48986;
BS406348;
BS419277
KEGG:
R02685;
R09698
MetaCyc:
ENOYL-COA-HYDRAT-RXN;
RXN-19190;
RXN-7699
|
|
|
|
acetyl-CoA + propionyl-CoA <=> 3-oxopentanoyl-CoA + CoA
|
2.3.1.16
acetyl-CoA C-acyltransferase
2.3.1.9
acetyl-CoA C-acetyltransferase
|
–
–
|
| |
BRENDA:
BS320551
MetaCyc:
RXN-12561
|
|
|
|
4-(phosphooxy)pentanoyl-CoA <=> beta-methylvinylacetyl-CoA + phosphate
|
not assigned
|
–
|
| |
MetaCyc:
RXN-19188
|
|
|
|
(R)-3-hydroxyvaleryl-CoA + NADP+ <=> 3-oxopentanoyl-CoA + NADPH + H+
|
1.1.1.36
acetoacetyl-CoA reductase
|
–
|
| |
MetaCyc:
RXN-12560
|
|
|
|
4-hydroxypentanoyl-CoA + ATP <=> 4-(phosphooxy)pentanoyl-CoA + ADP + H+
|
2.7.1.M16
|
–
|
| |
MetaCyc:
RXN-19187
|
|
