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(1'S,5'S)-averufin biosynthesis

State Icon Reaction EC-Number Confidence maximal confidence score from EnzymeDetector
(1''S)-averantin + reduced_[NADPH-hemoprotein_reductase] + O2 <=> (1''S,5''S)-hydroxyaverantin + oxidized_[NADPH-hemoprotein_reductase] + H2O 1.14.14.116 averantin hydroxylase

norsolorinic_acid_anthrone + O2 <=> norsolorinic_acid + H2O 1.13.12.20 noranthrone monooxygenase

hexanoyl-[acyl-carrier_protein] + malonyl-CoA + H+ <=> norsolorinic_acid_anthrone + [acyl-carrier_protein] + CoA + CO2 + H2O 2.3.1.221 noranthrone synthase

(1''S,5''S)-hydroxyaverantin + NAD+ <=> H+ + 5''-oxoaverantin + NADH 1.1.1.352 5'-hydroxyaverantin dehydrogenase

(1''S)-averantin + NADP+ <=> norsolorinic_acid + NADPH + H+ 1.1.1.349 norsolorinic acid ketoreductase
1.1.1.B25


(1''S,5''R)-hydroxyaverantin + NAD+ <=> H+ + 5''-oxoaverantin + NADH 1.1.1.352 5'-hydroxyaverantin dehydrogenase

(1''S)-averantin + reduced_[NADPH-hemoprotein_reductase] + O2 <=> (1''S,5''R)-hydroxyaverantin + oxidized_[NADPH-hemoprotein_reductase] + H2O 1.14.14.116 averantin hydroxylase

H+ + 5''-oxoaverantin <=> (1''S,5''S)-averufin + H2O 4.2.1.142 5'-oxoaverantin cyclase

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