|
|
(1''S)-averantin + reduced_[NADPH-hemoprotein_reductase] + O2 <=> (1''S,5''S)-hydroxyaverantin + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
1.14.14.116
averantin hydroxylase
|
–
|
| |
MetaCyc:
RXN-9481
|
|
|
|
norsolorinic_acid_anthrone + O2 <=> norsolorinic_acid + H2O
|
1.13.12.20
noranthrone monooxygenase
|
–
|
| |
BRENDA:
BR50371
KEGG:
R10224
MetaCyc:
RXN-11624
|
|
|
|
hexanoyl-[acyl-carrier_protein] + malonyl-CoA + H+ <=> norsolorinic_acid_anthrone + [acyl-carrier_protein] + CoA + CO2 + H2O
|
2.3.1.221
noranthrone synthase
|
–
|
| |
BRENDA:
BR50415
KEGG:
R10239
MetaCyc:
RXN-9479
|
|
|
|
(1''S,5''S)-hydroxyaverantin + NAD+ <=> H+ + 5''-oxoaverantin + NADH
|
1.1.1.352
5'-hydroxyaverantin dehydrogenase
|
–
|
| |
BRENDA:
BR50502
KEGG:
R10310
MetaCyc:
RXN-9483
|
|
|
|
(1''S)-averantin + NADP+ <=> norsolorinic_acid + NADPH + H+
|
1.1.1.349
norsolorinic acid ketoreductase
1.1.1.B25
|
–
–
|
| |
BRENDA:
BR50499
KEGG:
R10309
MetaCyc:
RXN-9480
|
|
|
|
(1''S,5''R)-hydroxyaverantin + NAD+ <=> H+ + 5''-oxoaverantin + NADH
|
1.1.1.352
5'-hydroxyaverantin dehydrogenase
|
–
|
| |
BRENDA:
BR50503
KEGG:
R10311
MetaCyc:
RXN-9484
|
|
|
|
(1''S)-averantin + reduced_[NADPH-hemoprotein_reductase] + O2 <=> (1''S,5''R)-hydroxyaverantin + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
1.14.14.116
averantin hydroxylase
|
–
|
| |
MetaCyc:
RXN-9482
|
|
|
|
H+ + 5''-oxoaverantin <=> (1''S,5''S)-averufin + H2O
|
4.2.1.142
5'-oxoaverantin cyclase
|
–
|
| |
BRENDA:
BR50550
KEGG:
R10475
MetaCyc:
RXN-9485
|
|
